5,16-Difluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C34H12F4S6) - excitons of #2165

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 0.678 3.893 eV
S2 0.883 4.010 eV
S3 0.916 4.091 eV
S4 0.477 4.142 eV
S5 1.925 4.226 eV
S6 0.052 4.546 eV
S7 0.025 4.651 eV
S8 0.128 4.718 eV
S9 0.002 4.808 eV
S10 0.222 4.817 eV
S11 0.057 4.906 eV
S12 0.010 4.955 eV
S13 0.038 5.071 eV
S14 0.069 5.149 eV
S15 0.015 5.179 eV
S16 0.047 5.230 eV
S17 0.466 5.232 eV
S18 0.109 5.324 eV
S19 0.013 5.373 eV
S20 0.000 5.408 eV
S21 0.038 5.437 eV
S22 0.125 5.464 eV
S23 0.118 5.494 eV
S24 0.024 5.548 eV
S25 0.003 5.578 eV
S26 0.039 5.673 eV
S27 0.015 5.679 eV
S28 0.008 5.725 eV
S29 0.012 5.752 eV
S30 0.013 5.772 eV
S31 0.005 5.801 eV
S32 0.003 5.826 eV
S33 0.043 5.865 eV
S34 0.002 5.880 eV
S35 0.002 5.886 eV
S36 0.006 6.034 eV
S37 0.032 6.045 eV
S38 0.031 6.069 eV
S39 0.016 6.117 eV
S40 0.043 6.145 eV
S41 0.103 6.178 eV
S42 0.021 6.206 eV
S43 0.008 6.232 eV
S44 0.064 6.280 eV
S45 0.324 6.314 eV
S46 0.115 6.349 eV
S47 0.140 6.358 eV
S48 0.028 6.382 eV
S49 0.002 6.426 eV
S50 0.009 6.431 eV
S51 0.008 6.497 eV
S52 0.004 6.517 eV
S53 0.006 6.525 eV
S54 0.047 6.536 eV
S55 0.010 6.602 eV
S56 0.028 6.618 eV
S57 0.101 6.638 eV
S58 0.228 6.672 eV
S59 0.018 6.682 eV
S60 0.050 6.692 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -111324.68

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 13:15:38

Added 2026-09-15 08:26:15

Legacy ID None

System


Full Name 5,16-Difluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID138554434

Formula C34H12F4S6

Mass 688.8 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2165 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM