5-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C34H13F3S6) - excitons of #2166

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 0.824 3.910 eV
S2 0.966 3.995 eV
S3 0.535 4.085 eV
S4 0.714 4.142 eV
S5 1.766 4.240 eV
S6 0.027 4.539 eV
S7 0.015 4.659 eV
S8 0.207 4.715 eV
S9 0.013 4.794 eV
S10 0.138 4.814 eV
S11 0.043 4.895 eV
S12 0.003 4.976 eV
S13 0.061 5.097 eV
S14 0.046 5.148 eV
S15 0.020 5.192 eV
S16 0.387 5.249 eV
S17 0.002 5.303 eV
S18 0.005 5.321 eV
S19 0.096 5.353 eV
S20 0.127 5.397 eV
S21 0.280 5.456 eV
S22 0.066 5.491 eV
S23 0.017 5.515 eV
S24 0.030 5.541 eV
S25 0.021 5.595 eV
S26 0.019 5.640 eV
S27 0.079 5.661 eV
S28 0.003 5.689 eV
S29 0.018 5.710 eV
S30 0.009 5.753 eV
S31 0.029 5.768 eV
S32 0.022 5.809 eV
S33 0.010 5.896 eV
S34 0.021 5.919 eV
S35 0.001 5.929 eV
S36 0.009 6.039 eV
S37 0.023 6.061 eV
S38 0.003 6.078 eV
S39 0.011 6.131 eV
S40 0.006 6.150 eV
S41 0.088 6.198 eV
S42 0.016 6.200 eV
S43 0.016 6.228 eV
S44 0.225 6.284 eV
S45 0.065 6.299 eV
S46 0.043 6.334 eV
S47 0.097 6.340 eV
S48 0.321 6.358 eV
S49 0.008 6.390 eV
S50 0.002 6.434 eV
S51 0.036 6.495 eV
S52 0.046 6.527 eV
S53 0.007 6.538 eV
S54 0.005 6.562 eV
S55 0.008 6.597 eV
S56 0.014 6.603 eV
S57 0.084 6.615 eV
S58 0.226 6.633 eV
S59 0.074 6.667 eV
S60 0.032 6.689 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -108623.72

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 11:09:43

Added 2026-09-15 08:27:12

Legacy ID None

System


Full Name 5-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID138554435

Formula C34H13F3S6

Mass 670.8 u

Point Group C1

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2166 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM