7,18-Difluoro-6,17-bis(3-fluorothiophen-2-yl)-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C26H8F4S6) - excitons of #2169

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.065 3.509 eV
S2 A' 0.673 3.932 eV
S3 A' 0.004 4.107 eV
S4 A' 0.001 4.296 eV
S5 A" 0.000 4.664 eV
S6 A' 0.015 4.671 eV
S7 A' 0.559 4.705 eV
S8 A' 0.013 4.811 eV
S9 A" 0.000 4.848 eV
S10 A' 0.472 4.978 eV
S11 A' 0.019 5.158 eV
S12 A" 0.000 5.159 eV
S13 A" 0.000 5.225 eV
S14 A' 0.004 5.304 eV
S15 A' 0.043 5.310 eV
S16 A' 0.084 5.372 eV
S17 A' 0.034 5.412 eV
S18 A" 0.000 5.415 eV
S19 A' 0.031 5.482 eV
S20 A' 0.346 5.588 eV
S21 A" 0.000 5.632 eV
S22 A' 0.023 5.686 eV
S23 A" 0.000 5.718 eV
S24 A' 0.164 5.725 eV
S25 A' 0.412 5.775 eV
S26 A" 0.001 5.800 eV
S27 A' 0.013 5.825 eV
S28 A" 0.000 5.872 eV
S29 A' 0.059 5.961 eV
S30 A' 0.175 6.001 eV
S31 A" 0.000 6.088 eV
S32 A' 0.032 6.125 eV
S33 A' 0.040 6.247 eV
S34 A' 0.409 6.291 eV
S35 A" 0.001 6.309 eV
S36 A" 0.000 6.316 eV
S37 A' 0.009 6.360 eV
S38 A" 0.002 6.413 eV
S39 A" 0.000 6.458 eV
S40 A' 0.182 6.463 eV
S41 A' 0.050 6.495 eV
S42 A' 0.248 6.516 eV
S43 A' 0.054 6.565 eV
S44 A' 0.060 6.587 eV
S45 A" 0.001 6.591 eV
S46 A" 0.000 6.626 eV
S47 A' 0.001 6.635 eV
S48 A' 0.028 6.695 eV
S49 A' 0.006 6.758 eV
S50 A" 0.000 6.762 eV
S51 A" 0.001 6.839 eV
S52 A' 0.039 6.844 eV
S53 A' 0.001 6.886 eV
S54 A' 0.066 6.902 eV
S55 A" 0.001 6.939 eV
S56 A" 0.000 6.971 eV
S57 A' 0.009 6.979 eV
S58 A" 0.000 6.992 eV
S59 A" 0.000 6.999 eV
S60 A' 0.054 7.018 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -102964.16

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 02:21:45

Added 2026-09-15 08:29:17

Legacy ID None

System


Full Name 7,18-Difluoro-6,17-bis(3-fluorothiophen-2-yl)-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID138554438

Formula C26H8F4S6

Mass 588.7 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2169 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM