5,16-Difluoro-6,17-bis(3-fluorothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C26H8F4S6) - excitons of #2170

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.274 3.922 eV
S2 A' 0.240 4.046 eV
S3 A' 0.082 4.093 eV
S4 A' 0.004 4.196 eV
S5 A' 3.697 4.242 eV
S6 A" 0.000 4.687 eV
S7 A' 0.034 4.732 eV
S8 A' 0.212 4.817 eV
S9 A" 0.000 4.845 eV
S10 A' 0.001 4.962 eV
S11 A' 0.102 5.071 eV
S12 A" 0.000 5.132 eV
S13 A" 0.000 5.221 eV
S14 A' 0.073 5.306 eV
S15 A' 0.013 5.378 eV
S16 A" 0.000 5.380 eV
S17 A' 0.111 5.422 eV
S18 A' 0.060 5.476 eV
S19 A' 0.084 5.555 eV
S20 A' 0.126 5.619 eV
S21 A' 0.016 5.628 eV
S22 A" 0.000 5.649 eV
S23 A' 0.146 5.728 eV
S24 A" 0.000 5.735 eV
S25 A' 0.011 5.794 eV
S26 A" 0.001 5.799 eV
S27 A' 0.040 5.834 eV
S28 A" 0.000 5.858 eV
S29 A' 0.008 5.954 eV
S30 A' 0.021 5.985 eV
S31 A" 0.000 6.022 eV
S32 A' 0.015 6.074 eV
S33 A' 0.132 6.166 eV
S34 A' 0.149 6.190 eV
S35 A" 0.001 6.313 eV
S36 A' 0.008 6.315 eV
S37 A" 0.001 6.342 eV
S38 A' 0.004 6.378 eV
S39 A" 0.000 6.426 eV
S40 A" 0.000 6.494 eV
S41 A' 0.036 6.533 eV
S42 A" 0.000 6.591 eV
S43 A' 0.006 6.603 eV
S44 A' 0.076 6.630 eV
S45 A" 0.000 6.662 eV
S46 A' 0.317 6.673 eV
S47 A' 0.024 6.707 eV
S48 A" 0.000 6.760 eV
S49 A' 0.026 6.772 eV
S50 A' 0.006 6.797 eV
S51 A" 0.000 6.814 eV
S52 A' 0.027 6.833 eV
S53 A' 0.009 6.862 eV
S54 A' 0.031 6.886 eV
S55 A" 0.005 6.889 eV
S56 A' 0.031 6.964 eV
S57 A" 0.000 6.966 eV
S58 A" 0.003 7.008 eV
S59 A" 0.000 7.015 eV
S60 A' 0.006 7.051 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -102964.11

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 02:38:11

Added 2026-09-15 08:29:55

Legacy ID None

System


Full Name 5,16-Difluoro-6,17-bis(3-fluorothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID138554439

Formula C26H8F4S6

Mass 588.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2170 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM