Decacyclo[28.12.0.02,15.04,13.06,11.016,29.018,27.020,25.032,41.034,39]dotetraconta-1(42),2,4,6,8,10,12,14,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaene (C42H24) - excitons of #2182

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 B1 0.000 3.182 eV
S2 B1 0.055 3.426 eV
S3 A1 0.055 3.426 eV
S4 A1 0.000 3.571 eV
S5 B1 0.001 3.604 eV
S6 A1 0.001 3.605 eV
S7 B1 0.000 3.992 eV
S8 A1 2.751 4.188 eV
S9 B1 2.752 4.188 eV
S10 B1 0.086 4.406 eV
S11 A1 0.085 4.407 eV
S12 B1 0.000 4.775 eV
S13 A1 0.127 4.782 eV
S14 B1 0.127 4.782 eV
S15 A1 0.000 4.919 eV
S16 A1 0.096 4.968 eV
S17 B1 0.095 4.968 eV
S18 B1 0.000 4.988 eV
S19 A1 1.667 5.205 eV
S20 B1 1.669 5.205 eV
S21 A1 0.000 5.322 eV
S22 B1 0.012 5.475 eV
S23 B1 0.047 5.476 eV
S24 A1 0.059 5.476 eV
S25 B1 0.087 5.573 eV
S26 A1 0.087 5.573 eV
S27 B1 0.000 5.616 eV
S28 A1 0.013 5.689 eV
S29 B1 0.013 5.689 eV
S30 B1 0.000 5.707 eV
S31 A1 0.000 5.734 eV
S32 B1 0.003 5.808 eV
S33 A1 0.003 5.808 eV
S34 A1 0.000 6.024 eV
S35 B1 0.000 6.047 eV
S36 A1 0.275 6.122 eV
S37 B1 0.275 6.122 eV
S38 B1 0.019 6.167 eV
S39 A1 0.020 6.167 eV
S40 B2 0.000 6.261 eV
S41 A2 0.000 6.261 eV
S42 B2 0.000 6.296 eV
S43 A2 0.000 6.297 eV
S44 B1 0.153 6.297 eV
S45 A1 0.153 6.297 eV
S46 A1 0.000 6.346 eV
S47 A1 0.107 6.364 eV
S48 B1 0.107 6.364 eV
S49 B2 0.000 6.406 eV
S50 A1 0.092 6.408 eV
S51 B1 0.092 6.408 eV
S52 B1 0.000 6.433 eV
S53 A2 0.000 6.454 eV
S54 A1 0.028 6.497 eV
S55 B1 0.029 6.497 eV
S56 A1 0.000 6.515 eV
S57 B1 0.000 6.539 eV
S58 A1 0.000 6.566 eV
S59 B2 0.000 6.609 eV
S60 A2 0.000 6.616 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -43929.87

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 20:03:48

Added 2026-09-15 08:40:57

Legacy ID None

System


Full Name Decacyclo[28.12.0.02,15.04,13.06,11.016,29.018,27.020,25.032,41.034,39]dotetraconta-1(42),2,4,6,8,10,12,14,16,18,20,22,24,26,28,30,32,34,36,38,40-henicosaene

Short Name anthra[2,3-j]heptaphene

Formula C42H24

Mass 528.7 u

Point Group C2v

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2182 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM