6,17-Bis(3,4-difluorothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C26H8F4S6) - excitons of #2188

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.335 3.931 eV
S2 A' 0.533 4.007 eV
S3 A' 0.043 4.050 eV
S4 A' 0.522 4.197 eV
S5 A' 2.633 4.239 eV
S6 A' 0.110 4.747 eV
S7 A" 0.000 4.779 eV
S8 A' 0.134 4.780 eV
S9 A' 0.007 4.949 eV
S10 A" 0.000 4.982 eV
S11 A' 0.047 5.100 eV
S12 A" 0.000 5.193 eV
S13 A" 0.000 5.322 eV
S14 A' 0.157 5.338 eV
S15 A' 0.052 5.346 eV
S16 A' 0.015 5.382 eV
S17 A' 0.105 5.426 eV
S18 A' 0.059 5.470 eV
S19 A" 0.000 5.487 eV
S20 A' 0.227 5.574 eV
S21 A" 0.000 5.592 eV
S22 A" 0.000 5.660 eV
S23 A' 0.100 5.692 eV
S24 A' 0.078 5.705 eV
S25 A' 0.015 5.775 eV
S26 A' 0.036 5.814 eV
S27 A" 0.000 5.841 eV
S28 A" 0.000 5.906 eV
S29 A' 0.166 5.950 eV
S30 A' 0.010 6.030 eV
S31 A" 0.001 6.059 eV
S32 A" 0.000 6.092 eV
S33 A' 0.003 6.152 eV
S34 A' 0.085 6.214 eV
S35 A" 0.000 6.222 eV
S36 A' 0.205 6.272 eV
S37 A' 0.008 6.314 eV
S38 A" 0.000 6.343 eV
S39 A' 0.010 6.396 eV
S40 A" 0.001 6.436 eV
S41 A" 0.000 6.463 eV
S42 A' 0.014 6.510 eV
S43 A' 0.010 6.551 eV
S44 A" 0.000 6.638 eV
S45 A' 0.203 6.640 eV
S46 A' 0.229 6.683 eV
S47 A" 0.000 6.684 eV
S48 A' 0.001 6.708 eV
S49 A" 0.000 6.723 eV
S50 A' 0.014 6.768 eV
S51 A' 0.013 6.850 eV
S52 A" 0.000 6.853 eV
S53 A' 0.024 6.860 eV
S54 A" 0.005 6.902 eV
S55 A' 0.014 6.903 eV
S56 A' 0.010 6.920 eV
S57 A" 0.004 6.979 eV
S58 A" 0.004 6.997 eV
S59 A' 0.064 7.018 eV
S60 A" 0.009 7.043 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -102963.99

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 02:57:46

Added 2026-09-15 08:47:48

Legacy ID None

System


Full Name 6,17-Bis(3,4-difluorothiophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID138554605

Formula C26H8F4S6

Mass 588.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2188 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM