7,18-Difluoro-6-(3-fluorothiophen-2-yl)-17-thiophen-2-yl-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C26H9F3S6) - excitons of #2194

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.152 3.502 eV
S2 A' 0.598 3.925 eV
S3 A' 0.003 4.105 eV
S4 A' 0.001 4.282 eV
S5 A" 0.000 4.662 eV
S6 A' 0.011 4.665 eV
S7 A' 0.594 4.691 eV
S8 A" 0.000 4.779 eV
S9 A' 0.000 4.783 eV
S10 A" 0.000 4.917 eV
S11 A' 0.330 4.967 eV
S12 A" 0.000 5.169 eV
S13 A' 0.044 5.184 eV
S14 A" 0.000 5.278 eV
S15 A' 0.043 5.287 eV
S16 A' 0.006 5.305 eV
S17 A' 0.006 5.325 eV
S18 A" 0.000 5.411 eV
S19 A' 0.167 5.439 eV
S20 A' 0.051 5.500 eV
S21 A' 0.492 5.582 eV
S22 A" 0.000 5.663 eV
S23 A' 0.000 5.686 eV
S24 A' 0.022 5.706 eV
S25 A' 0.466 5.752 eV
S26 A" 0.001 5.802 eV
S27 A' 0.003 5.818 eV
S28 A' 0.231 5.984 eV
S29 A' 0.013 6.020 eV
S30 A" 0.000 6.045 eV
S31 A" 0.000 6.108 eV
S32 A' 0.002 6.125 eV
S33 A' 0.096 6.271 eV
S34 A" 0.000 6.309 eV
S35 A' 0.311 6.327 eV
S36 A" 0.000 6.376 eV
S37 A' 0.007 6.390 eV
S38 A" 0.002 6.413 eV
S39 A' 0.232 6.444 eV
S40 A" 0.001 6.452 eV
S41 A" 0.000 6.493 eV
S42 A' 0.043 6.502 eV
S43 A' 0.048 6.530 eV
S44 A' 0.046 6.543 eV
S45 A' 0.020 6.577 eV
S46 A' 0.330 6.592 eV
S47 A" 0.000 6.606 eV
S48 A" 0.000 6.676 eV
S49 A' 0.001 6.681 eV
S50 A' 0.030 6.727 eV
S51 A" 0.000 6.788 eV
S52 A' 0.012 6.824 eV
S53 A' 0.010 6.878 eV
S54 A' 0.004 6.911 eV
S55 A" 0.000 6.912 eV
S56 A" 0.000 6.930 eV
S57 A" 0.003 6.958 eV
S58 A" 0.000 6.986 eV
S59 A' 0.055 6.989 eV
S60 A' 0.006 7.008 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -100263.18

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 23:45:13

Added 2026-09-15 08:51:58

Legacy ID None

System


Full Name 7,18-Difluoro-6-(3-fluorothiophen-2-yl)-17-thiophen-2-yl-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID138554857

Formula C26H9F3S6

Mass 570.7 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2194 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM