6,17-Bis(3,4-difluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C26H8F4S4Se2) - excitons of #2208

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.308 3.937 eV
S2 A' 0.109 3.977 eV
S3 A' 0.360 3.995 eV
S4 A' 0.896 4.175 eV
S5 A' 2.373 4.204 eV
S6 A" 0.000 4.396 eV
S7 A' 0.266 4.671 eV
S8 A' 0.070 4.715 eV
S9 A" 0.000 4.720 eV
S10 A" 0.000 4.793 eV
S11 A' 0.007 4.866 eV
S12 A" 0.000 4.904 eV
S13 A' 0.041 4.941 eV
S14 A' 0.101 5.296 eV
S15 A' 0.054 5.297 eV
S16 A" 0.000 5.320 eV
S17 A' 0.023 5.337 eV
S18 A' 0.074 5.368 eV
S19 A" 0.000 5.392 eV
S20 A' 0.094 5.403 eV
S21 A' 0.108 5.490 eV
S22 A" 0.000 5.597 eV
S23 A' 0.283 5.613 eV
S24 A' 0.018 5.653 eV
S25 A' 0.008 5.659 eV
S26 A" 0.000 5.673 eV
S27 A" 0.000 5.706 eV
S28 A' 0.031 5.776 eV
S29 A' 0.128 5.876 eV
S30 A' 0.011 5.943 eV
S31 A" 0.000 5.969 eV
S32 A' 0.006 6.053 eV
S33 A" 0.000 6.056 eV
S34 A" 0.001 6.069 eV
S35 A' 0.034 6.129 eV
S36 A" 0.000 6.141 eV
S37 A" 0.001 6.194 eV
S38 A' 0.183 6.207 eV
S39 A' 0.011 6.254 eV
S40 A' 0.002 6.290 eV
S41 A" 0.000 6.294 eV
S42 A" 0.000 6.391 eV
S43 A' 0.002 6.405 eV
S44 A' 0.014 6.433 eV
S45 A" 0.000 6.479 eV
S46 A' 0.108 6.524 eV
S47 A" 0.000 6.541 eV
S48 A" 0.001 6.573 eV
S49 A' 0.127 6.582 eV
S50 A' 0.014 6.624 eV
S51 A' 0.026 6.701 eV
S52 A" 0.000 6.713 eV
S53 A" 0.000 6.737 eV
S54 A' 0.108 6.750 eV
S55 A' 0.020 6.789 eV
S56 A" 0.003 6.797 eV
S57 A" 0.000 6.820 eV
S58 A" 0.001 6.840 eV
S59 A" 0.000 6.866 eV
S60 A" 0.002 6.906 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -211997.70

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 11:29:32

Added 2026-09-15 09:04:19

Legacy ID None

System


Full Name 6,17-Bis(3,4-difluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID141654996

Formula C26H8F4S4Se2

Mass 682.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2208 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM