7,18-Difluoro-6-(3-fluorothiophen-2-yl)-17-thiophen-2-yl-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C26H9F3S4Se2) - excitons of #2209

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.217 3.484 eV
S2 A' 0.578 3.896 eV
S3 A' 0.004 4.028 eV
S4 A" 0.000 4.194 eV
S5 A' 0.001 4.265 eV
S6 A" 0.000 4.299 eV
S7 A' 0.369 4.652 eV
S8 A' 0.000 4.669 eV
S9 A" 0.000 4.681 eV
S10 A' 0.001 4.734 eV
S11 A" 0.000 4.782 eV
S12 A' 0.410 4.831 eV
S13 A" 0.000 4.880 eV
S14 A' 0.059 5.163 eV
S15 A' 0.027 5.206 eV
S16 A' 0.028 5.241 eV
S17 A' 0.000 5.282 eV
S18 A' 0.157 5.402 eV
S19 A" 0.000 5.413 eV
S20 A' 0.052 5.453 eV
S21 A' 0.731 5.503 eV
S22 A" 0.000 5.594 eV
S23 A' 0.082 5.629 eV
S24 A' 0.014 5.634 eV
S25 A" 0.000 5.650 eV
S26 A' 0.135 5.695 eV
S27 A' 0.007 5.713 eV
S28 A" 0.000 5.883 eV
S29 A' 0.216 5.894 eV
S30 A" 0.000 5.908 eV
S31 A' 0.006 5.953 eV
S32 A" 0.000 5.992 eV
S33 A' 0.003 6.051 eV
S34 A" 0.002 6.069 eV
S35 A" 0.000 6.137 eV
S36 A" 0.001 6.175 eV
S37 A" 0.000 6.201 eV
S38 A' 0.081 6.212 eV
S39 A' 0.188 6.266 eV
S40 A' 0.201 6.284 eV
S41 A" 0.000 6.352 eV
S42 A' 0.380 6.384 eV
S43 A' 0.018 6.417 eV
S44 A' 0.001 6.450 eV
S45 A' 0.027 6.472 eV
S46 A' 0.001 6.527 eV
S47 A" 0.000 6.560 eV
S48 A' 0.155 6.573 eV
S49 A" 0.000 6.617 eV
S50 A' 0.017 6.618 eV
S51 A' 0.048 6.630 eV
S52 A" 0.000 6.679 eV
S53 A' 0.010 6.721 eV
S54 A" 0.000 6.725 eV
S55 A" 0.001 6.755 eV
S56 A" 0.000 6.771 eV
S57 A' 0.014 6.791 eV
S58 A" 0.000 6.821 eV
S59 A' 0.003 6.835 eV
S60 A" 0.000 6.837 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -209296.96

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 09:59:31

Added 2026-09-15 09:05:02

Legacy ID None

System


Full Name 7,18-Difluoro-6-(3-fluorothiophen-2-yl)-17-thiophen-2-yl-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141654997

Formula C26H9F3S4Se2

Mass 664.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2209 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM