5,16-Difluoro-6,17-di(selenophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13,15(19),16,20-nonaene (C26H10F2S2Se4) - excitons of #2211

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 1.042 3.911 eV
S2 A' 0.003 3.992 eV
S3 A' 0.000 4.020 eV
S4 A' 0.019 4.102 eV
S5 A' 2.892 4.137 eV
S6 A" 0.000 4.181 eV
S7 A" 0.000 4.477 eV
S8 A" 0.000 4.547 eV
S9 A' 0.008 4.595 eV
S10 A' 0.410 4.661 eV
S11 A' 0.001 4.860 eV
S12 A" 0.000 4.876 eV
S13 A' 0.064 4.908 eV
S14 A" 0.000 4.981 eV
S15 A' 0.126 5.065 eV
S16 A' 0.090 5.091 eV
S17 A" 0.000 5.163 eV
S18 A' 0.138 5.227 eV
S19 A' 0.018 5.283 eV
S20 A" 0.000 5.386 eV
S21 A' 0.008 5.396 eV
S22 A" 0.000 5.425 eV
S23 A' 0.034 5.438 eV
S24 A' 0.002 5.558 eV
S25 A' 0.389 5.616 eV
S26 A' 0.068 5.633 eV
S27 A" 0.000 5.639 eV
S28 A' 0.040 5.727 eV
S29 A" 0.000 5.733 eV
S30 A' 0.001 5.853 eV
S31 A" 0.001 5.856 eV
S32 A' 0.011 5.895 eV
S33 A" 0.000 5.953 eV
S34 A' 0.002 5.966 eV
S35 A" 0.000 5.999 eV
S36 A' 0.001 6.028 eV
S37 A' 0.160 6.077 eV
S38 A' 0.067 6.163 eV
S39 A" 0.000 6.183 eV
S40 A' 0.006 6.223 eV
S41 A" 0.001 6.243 eV
S42 A" 0.000 6.285 eV
S43 A' 0.001 6.375 eV
S44 A' 0.020 6.404 eV
S45 A' 0.033 6.416 eV
S46 A" 0.000 6.425 eV
S47 A' 0.006 6.453 eV
S48 A' 0.013 6.480 eV
S49 A" 0.000 6.529 eV
S50 A' 0.123 6.562 eV
S51 A" 0.001 6.576 eV
S52 A" 0.000 6.588 eV
S53 A' 0.024 6.615 eV
S54 A" 0.000 6.615 eV
S55 A" 0.003 6.644 eV
S56 A" 0.001 6.649 eV
S57 A' 0.171 6.680 eV
S58 A" 0.002 6.695 eV
S59 A' 0.016 6.708 eV
S60 A" 0.001 6.713 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -315629.69

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 15:25:10

Added 2026-09-15 09:06:23

Legacy ID None

System


Full Name 5,16-Difluoro-6,17-di(selenophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13,15(19),16,20-nonaene

Short Name CID141655001

Formula C26H10F2S2Se4

Mass 740.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2211 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM