5-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene (C34H13F3S2Se4) - excitons of #2214

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.001 3.845 eV
S2 A' 0.473 3.927 eV
S3 A' 0.098 3.946 eV
S4 A' 0.010 4.054 eV
S5 A' 2.306 4.101 eV
S6 A' 0.011 4.363 eV
S7 A' 0.068 4.371 eV
S8 A" 0.000 4.587 eV
S9 A' 0.083 4.607 eV
S10 A" 0.000 4.650 eV
S11 A' 0.297 4.668 eV
S12 A" 0.000 4.742 eV
S13 A" 0.000 4.766 eV
S14 A' 0.018 4.797 eV
S15 A' 0.052 4.884 eV
S16 A" 0.000 4.901 eV
S17 A" 0.000 5.038 eV
S18 A' 0.020 5.100 eV
S19 A" 0.000 5.171 eV
S20 A' 0.190 5.172 eV
S21 A' 0.095 5.249 eV
S22 A" 0.000 5.255 eV
S23 A' 0.049 5.266 eV
S24 A' 0.015 5.296 eV
S25 A" 0.000 5.316 eV
S26 A' 0.189 5.362 eV
S27 A" 0.000 5.400 eV
S28 A' 0.467 5.452 eV
S29 A' 0.123 5.488 eV
S30 A' 0.030 5.569 eV
S31 A' 0.007 5.619 eV
S32 A' 0.009 5.658 eV
S33 A' 0.006 5.674 eV
S34 A" 0.000 5.691 eV
S35 A' 0.014 5.775 eV
S36 A' 0.015 5.811 eV
S37 A' 0.030 5.877 eV
S38 A' 0.001 5.900 eV
S39 A" 0.000 5.918 eV
S40 A' 0.005 5.975 eV
S41 A" 0.000 6.009 eV
S42 A' 0.001 6.037 eV
S43 A' 0.009 6.082 eV
S44 A' 0.057 6.097 eV
S45 A' 0.014 6.125 eV
S46 A" 0.000 6.132 eV
S47 A' 0.101 6.157 eV
S48 A' 0.036 6.173 eV
S49 A' 0.261 6.218 eV
S50 A' 0.249 6.254 eV
S51 A" 0.000 6.283 eV
S52 A" 0.000 6.286 eV
S53 A' 0.008 6.297 eV
S54 A' 0.013 6.320 eV
S55 A" 0.000 6.353 eV
S56 A' 0.019 6.361 eV
S57 A" 0.002 6.368 eV
S58 A' 0.004 6.374 eV
S59 A' 0.020 6.431 eV
S60 A" 0.000 6.449 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -326691.27

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-12 01:27:26

Added 2026-09-15 09:09:15

Legacy ID None

System


Full Name 5-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene

Short Name CID141655006

Formula C34H13F3S2Se4

Mass 858.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2214 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM