5-Fluoro-6,17-bis(3-fluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene (C26H9F3S4Se2) - excitons of #2215

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.448 3.980 eV
S2 A' 0.003 4.007 eV
S3 A' 0.023 4.039 eV
S4 A" 0.000 4.188 eV
S5 A' 2.693 4.202 eV
S6 A' 1.108 4.210 eV
S7 A" 0.000 4.408 eV
S8 A" 0.000 4.650 eV
S9 A' 0.173 4.661 eV
S10 A' 0.153 4.696 eV
S11 A" 0.000 4.773 eV
S12 A" 0.000 4.870 eV
S13 A' 0.016 4.876 eV
S14 A' 0.026 4.997 eV
S15 A' 0.026 5.266 eV
S16 A' 0.007 5.330 eV
S17 A' 0.029 5.366 eV
S18 A" 0.000 5.381 eV
S19 A' 0.221 5.430 eV
S20 A' 0.002 5.502 eV
S21 A' 0.060 5.527 eV
S22 A" 0.000 5.611 eV
S23 A' 0.001 5.632 eV
S24 A" 0.000 5.644 eV
S25 A' 0.008 5.647 eV
S26 A' 0.177 5.688 eV
S27 A" 0.001 5.782 eV
S28 A' 0.090 5.797 eV
S29 A' 0.026 5.868 eV
S30 A" 0.000 5.899 eV
S31 A' 0.002 5.939 eV
S32 A" 0.000 5.969 eV
S33 A' 0.001 6.033 eV
S34 A' 0.034 6.078 eV
S35 A" 0.001 6.093 eV
S36 A" 0.000 6.124 eV
S37 A' 0.091 6.144 eV
S38 A" 0.000 6.148 eV
S39 A" 0.000 6.218 eV
S40 A' 0.026 6.247 eV
S41 A' 0.002 6.278 eV
S42 A' 0.009 6.457 eV
S43 A" 0.000 6.460 eV
S44 A' 0.009 6.479 eV
S45 A' 0.035 6.520 eV
S46 A" 0.001 6.529 eV
S47 A' 0.303 6.558 eV
S48 A" 0.001 6.572 eV
S49 A" 0.001 6.616 eV
S50 A' 0.039 6.627 eV
S51 A' 0.023 6.672 eV
S52 A" 0.000 6.677 eV
S53 A' 0.125 6.718 eV
S54 A" 0.001 6.725 eV
S55 A' 0.004 6.738 eV
S56 A" 0.002 6.738 eV
S57 A' 0.051 6.792 eV
S58 A" 0.002 6.799 eV
S59 A" 0.000 6.856 eV
S60 A" 0.000 6.860 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -209296.89

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 10:06:46

Added 2026-09-15 09:10:18

Legacy ID None

System


Full Name 5-Fluoro-6,17-bis(3-fluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene

Short Name CID141655007

Formula C26H9F3S4Se2

Mass 664.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2215 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM