6,17-Bis(3,4-difluorothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C26H8F4S4Se2) - excitons of #2221

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.095 3.479 eV
S2 A' 0.687 3.876 eV
S3 A' 0.009 4.009 eV
S4 A' 0.003 4.244 eV
S5 A" 0.000 4.402 eV
S6 A' 0.150 4.646 eV
S7 A' 0.108 4.658 eV
S8 A" 0.000 4.722 eV
S9 A' 0.002 4.752 eV
S10 A" 0.000 4.798 eV
S11 A' 0.308 4.839 eV
S12 A" 0.000 4.919 eV
S13 A' 0.135 5.125 eV
S14 A' 0.007 5.166 eV
S15 A' 0.047 5.212 eV
S16 A' 0.050 5.271 eV
S17 A' 0.038 5.310 eV
S18 A" 0.000 5.324 eV
S19 A' 0.042 5.377 eV
S20 A" 0.000 5.397 eV
S21 A' 0.430 5.497 eV
S22 A' 0.721 5.567 eV
S23 A" 0.000 5.574 eV
S24 A" 0.000 5.671 eV
S25 A' 0.002 5.681 eV
S26 A' 0.003 5.705 eV
S27 A" 0.000 5.709 eV
S28 A' 0.006 5.798 eV
S29 A' 0.216 5.919 eV
S30 A" 0.000 5.941 eV
S31 A' 0.002 5.962 eV
S32 A" 0.001 6.060 eV
S33 A" 0.000 6.075 eV
S34 A' 0.100 6.077 eV
S35 A' 0.099 6.104 eV
S36 A" 0.000 6.124 eV
S37 A" 0.001 6.206 eV
S38 A' 0.082 6.241 eV
S39 A" 0.000 6.278 eV
S40 A' 0.540 6.302 eV
S41 A' 0.123 6.364 eV
S42 A" 0.000 6.390 eV
S43 A' 0.001 6.417 eV
S44 A' 0.003 6.497 eV
S45 A' 0.006 6.528 eV
S46 A" 0.001 6.538 eV
S47 A' 0.091 6.544 eV
S48 A" 0.000 6.560 eV
S49 A' 0.049 6.591 eV
S50 A" 0.000 6.628 eV
S51 A' 0.004 6.675 eV
S52 A" 0.002 6.694 eV
S53 A' 0.047 6.702 eV
S54 A" 0.000 6.705 eV
S55 A' 0.025 6.733 eV
S56 A" 0.000 6.745 eV
S57 A" 0.000 6.784 eV
S58 A' 0.020 6.813 eV
S59 A" 0.000 6.821 eV
S60 A' 0.004 6.841 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -211997.78

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 11:59:41

Added 2026-09-15 09:15:17

Legacy ID None

System


Full Name 6,17-Bis(3,4-difluorothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141655017

Formula C26H8F4S4Se2

Mass 682.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2221 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM