7-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C34H13F3S4Se2) - excitons of #2223

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.845 3.405 eV
S2 A' 0.740 3.831 eV
S3 A' 0.004 3.972 eV
S4 A' 0.000 4.143 eV
S5 A' 0.003 4.469 eV
S6 A' 0.095 4.490 eV
S7 A' 0.053 4.571 eV
S8 A" 0.000 4.579 eV
S9 A' 0.271 4.637 eV
S10 A' 0.004 4.712 eV
S11 A" 0.000 4.746 eV
S12 A' 0.296 4.780 eV
S13 A" 0.000 4.933 eV
S14 A' 0.322 5.034 eV
S15 A' 0.007 5.075 eV
S16 A' 0.014 5.130 eV
S17 A" 0.000 5.196 eV
S18 A' 0.008 5.221 eV
S19 A' 0.010 5.246 eV
S20 A" 0.000 5.308 eV
S21 A" 0.000 5.313 eV
S22 A' 0.078 5.339 eV
S23 A" 0.000 5.404 eV
S24 A" 0.000 5.411 eV
S25 A' 0.212 5.419 eV
S26 A' 0.348 5.496 eV
S27 A' 0.045 5.571 eV
S28 A' 0.363 5.622 eV
S29 A" 0.000 5.633 eV
S30 A' 0.244 5.651 eV
S31 A' 0.017 5.687 eV
S32 A" 0.000 5.695 eV
S33 A' 0.056 5.766 eV
S34 A' 0.009 5.795 eV
S35 A" 0.000 5.839 eV
S36 A' 0.327 5.853 eV
S37 A' 0.279 5.952 eV
S38 A' 0.018 5.988 eV
S39 A" 0.000 6.049 eV
S40 A' 0.193 6.068 eV
S41 A' 0.339 6.099 eV
S42 A' 0.005 6.134 eV
S43 A' 0.090 6.197 eV
S44 A' 0.073 6.233 eV
S45 A' 0.192 6.251 eV
S46 A" 0.001 6.259 eV
S47 A' 0.091 6.278 eV
S48 A' 0.132 6.325 eV
S49 A" 0.001 6.350 eV
S50 A' 0.009 6.384 eV
S51 A' 0.027 6.396 eV
S52 A" 0.000 6.422 eV
S53 A' 0.036 6.432 eV
S54 A' 0.000 6.465 eV
S55 A" 0.000 6.480 eV
S56 A" 0.001 6.500 eV
S57 A' 0.030 6.508 eV
S58 A' 0.007 6.566 eV
S59 A' 0.002 6.612 eV
S60 A' 0.078 6.654 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -217657.45

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 18:06:50

Added 2026-09-15 09:16:51

Legacy ID None

System


Full Name 7-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141655025

Formula C34H13F3S4Se2

Mass 764.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2223 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM