6,17-Bis(3-fluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C26H10F2S4Se2) - excitons of #2230

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.483 3.970 eV
S2 A' 0.099 4.000 eV
S3 A' 0.116 4.030 eV
S4 A' 1.237 4.184 eV
S5 A' 2.131 4.210 eV
S6 A" 0.000 4.396 eV
S7 A' 0.211 4.676 eV
S8 A' 0.126 4.706 eV
S9 A" 0.000 4.729 eV
S10 A" 0.000 4.763 eV
S11 A" 0.000 4.904 eV
S12 A' 0.004 4.906 eV
S13 A' 0.041 4.984 eV
S14 A" 0.000 5.296 eV
S15 A' 0.027 5.298 eV
S16 A' 0.018 5.339 eV
S17 A' 0.009 5.364 eV
S18 A" 0.000 5.378 eV
S19 A' 0.119 5.425 eV
S20 A' 0.180 5.439 eV
S21 A' 0.070 5.510 eV
S22 A" 0.000 5.562 eV
S23 A' 0.269 5.612 eV
S24 A" 0.000 5.653 eV
S25 A' 0.032 5.660 eV
S26 A' 0.007 5.665 eV
S27 A" 0.001 5.784 eV
S28 A' 0.119 5.790 eV
S29 A' 0.040 5.832 eV
S30 A' 0.020 5.908 eV
S31 A" 0.000 5.954 eV
S32 A' 0.016 6.022 eV
S33 A" 0.000 6.069 eV
S34 A' 0.030 6.098 eV
S35 A' 0.077 6.133 eV
S36 A" 0.000 6.145 eV
S37 A" 0.001 6.154 eV
S38 A' 0.013 6.230 eV
S39 A' 0.036 6.270 eV
S40 A" 0.000 6.396 eV
S41 A' 0.003 6.420 eV
S42 A' 0.001 6.444 eV
S43 A" 0.000 6.471 eV
S44 A' 0.280 6.495 eV
S45 A" 0.000 6.510 eV
S46 A' 0.006 6.535 eV
S47 A" 0.001 6.544 eV
S48 A' 0.023 6.597 eV
S49 A' 0.029 6.666 eV
S50 A" 0.000 6.679 eV
S51 A" 0.001 6.684 eV
S52 A' 0.018 6.710 eV
S53 A" 0.000 6.733 eV
S54 A' 0.058 6.738 eV
S55 A" 0.001 6.775 eV
S56 A" 0.000 6.825 eV
S57 A" 0.003 6.826 eV
S58 A" 0.001 6.851 eV
S59 A' 0.030 6.877 eV
S60 A" 0.001 6.895 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -206596.01

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 08:51:45

Added 2026-09-15 09:23:40

Legacy ID None

System


Full Name 6,17-Bis(3-fluorothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID141655038

Formula C26H10F2S4Se2

Mass 646.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2230 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM