7-Fluoro-6,17-bis(3-fluorothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C26H9F3S4Se2) - excitons of #2232

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.165 3.496 eV
S2 A' 0.629 3.908 eV
S3 A' 0.011 4.046 eV
S4 A' 0.001 4.287 eV
S5 A" 0.000 4.412 eV
S6 A" 0.000 4.576 eV
S7 A' 0.163 4.634 eV
S8 A' 0.224 4.722 eV
S9 A' 0.001 4.755 eV
S10 A" 0.000 4.784 eV
S11 A' 0.411 4.872 eV
S12 A" 0.000 4.882 eV
S13 A' 0.049 5.150 eV
S14 A' 0.021 5.184 eV
S15 A" 0.000 5.214 eV
S16 A' 0.008 5.286 eV
S17 A' 0.003 5.323 eV
S18 A" 0.000 5.399 eV
S19 A' 0.035 5.404 eV
S20 A' 0.067 5.440 eV
S21 A' 0.646 5.512 eV
S22 A' 0.363 5.626 eV
S23 A" 0.000 5.626 eV
S24 A' 0.024 5.662 eV
S25 A" 0.001 5.698 eV
S26 A' 0.012 5.720 eV
S27 A' 0.015 5.757 eV
S28 A" 0.001 5.779 eV
S29 A' 0.125 5.900 eV
S30 A' 0.102 5.931 eV
S31 A" 0.000 5.985 eV
S32 A' 0.033 6.065 eV
S33 A" 0.000 6.085 eV
S34 A' 0.044 6.151 eV
S35 A" 0.000 6.177 eV
S36 A' 0.247 6.208 eV
S37 A' 0.067 6.271 eV
S38 A" 0.001 6.277 eV
S39 A" 0.001 6.326 eV
S40 A' 0.485 6.369 eV
S41 A" 0.000 6.372 eV
S42 A' 0.020 6.433 eV
S43 A' 0.024 6.451 eV
S44 A' 0.075 6.502 eV
S45 A' 0.012 6.519 eV
S46 A" 0.000 6.523 eV
S47 A' 0.007 6.568 eV
S48 A" 0.000 6.608 eV
S49 A' 0.002 6.655 eV
S50 A" 0.000 6.669 eV
S51 A' 0.072 6.692 eV
S52 A" 0.001 6.713 eV
S53 A" 0.000 6.742 eV
S54 A' 0.016 6.753 eV
S55 A" 0.000 6.758 eV
S56 A' 0.025 6.790 eV
S57 A' 0.011 6.832 eV
S58 A" 0.001 6.836 eV
S59 A" 0.001 6.844 eV
S60 A" 0.000 6.865 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -209297.08

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 10:50:25

Added 2026-09-15 09:25:04

Legacy ID None

System


Full Name 7-Fluoro-6,17-bis(3-fluorothiophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141655044

Formula C26H9F3S4Se2

Mass 664.5 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2232 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM