7-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C34H13F3S2Se4) - excitons of #2234

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.882 3.377 eV
S2 A' 0.690 3.826 eV
S3 A' 0.012 3.936 eV
S4 A' 0.017 4.121 eV
S5 A" 0.000 4.138 eV
S6 A' 0.033 4.326 eV
S7 A' 0.069 4.348 eV
S8 A" 0.000 4.486 eV
S9 A' 0.039 4.518 eV
S10 A" 0.000 4.588 eV
S11 A" 0.000 4.618 eV
S12 A' 0.272 4.633 eV
S13 A' 0.024 4.696 eV
S14 A" 0.000 4.763 eV
S15 A' 0.213 4.769 eV
S16 A" 0.000 4.877 eV
S17 A' 0.372 5.000 eV
S18 A' 0.001 5.051 eV
S19 A' 0.008 5.108 eV
S20 A' 0.038 5.173 eV
S21 A" 0.000 5.180 eV
S22 A' 0.009 5.195 eV
S23 A" 0.000 5.246 eV
S24 A' 0.011 5.291 eV
S25 A' 0.165 5.375 eV
S26 A" 0.000 5.395 eV
S27 A' 0.310 5.466 eV
S28 A' 0.179 5.505 eV
S29 A" 0.000 5.581 eV
S30 A' 0.489 5.583 eV
S31 A' 0.034 5.614 eV
S32 A' 0.110 5.647 eV
S33 A' 0.101 5.703 eV
S34 A' 0.270 5.746 eV
S35 A' 0.021 5.766 eV
S36 A" 0.000 5.768 eV
S37 A' 0.027 5.876 eV
S38 A" 0.000 5.907 eV
S39 A' 0.044 5.938 eV
S40 A' 0.201 5.948 eV
S41 A' 0.172 5.987 eV
S42 A" 0.000 6.049 eV
S43 A' 0.123 6.052 eV
S44 A' 0.135 6.116 eV
S45 A" 0.001 6.194 eV
S46 A' 0.004 6.195 eV
S47 A" 0.001 6.219 eV
S48 A' 0.086 6.227 eV
S49 A" 0.001 6.250 eV
S50 A' 0.111 6.252 eV
S51 A' 0.448 6.281 eV
S52 A" 0.000 6.306 eV
S53 A' 0.049 6.327 eV
S54 A" 0.000 6.332 eV
S55 A" 0.000 6.371 eV
S56 A' 0.052 6.371 eV
S57 A' 0.068 6.388 eV
S58 A' 0.010 6.433 eV
S59 A' 0.005 6.454 eV
S60 A" 0.000 6.491 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -326691.18

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 23:35:52

Added 2026-09-15 09:26:29

Legacy ID None

System


Full Name 7-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-11,22-dithia-5,16-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141655049

Formula C34H13F3S2Se4

Mass 858.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2234 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM