5-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C34H13F3S4Se2) - excitons of #2235

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 1.752 3.834 eV
S2 A' 0.860 3.954 eV
S3 A' 0.062 3.991 eV
S4 A' 0.012 4.071 eV
S5 A' 2.118 4.106 eV
S6 A" 0.000 4.230 eV
S7 A' 0.044 4.384 eV
S8 A' 0.112 4.426 eV
S9 A' 0.017 4.642 eV
S10 A" 0.000 4.649 eV
S11 A" 0.000 4.649 eV
S12 A' 0.323 4.721 eV
S13 A" 0.000 4.802 eV
S14 A' 0.012 4.879 eV
S15 A" 0.000 4.896 eV
S16 A' 0.066 5.022 eV
S17 A" 0.000 5.051 eV
S18 A' 0.142 5.129 eV
S19 A' 0.183 5.186 eV
S20 A' 0.088 5.263 eV
S21 A' 0.079 5.316 eV
S22 A" 0.000 5.323 eV
S23 A' 0.005 5.353 eV
S24 A' 0.329 5.439 eV
S25 A' 0.064 5.488 eV
S26 A" 0.000 5.524 eV
S27 A' 0.307 5.536 eV
S28 A' 0.007 5.612 eV
S29 A" 0.000 5.630 eV
S30 A' 0.057 5.686 eV
S31 A' 0.037 5.710 eV
S32 A' 0.002 5.743 eV
S33 A' 0.017 5.824 eV
S34 A' 0.003 5.858 eV
S35 A" 0.000 5.888 eV
S36 A' 0.019 5.895 eV
S37 A' 0.002 5.938 eV
S38 A" 0.000 6.007 eV
S39 A" 0.000 6.029 eV
S40 A' 0.009 6.073 eV
S41 A' 0.007 6.082 eV
S42 A" 0.000 6.082 eV
S43 A' 0.015 6.118 eV
S44 A' 0.026 6.140 eV
S45 A" 0.000 6.142 eV
S46 A' 0.260 6.200 eV
S47 A' 0.018 6.223 eV
S48 A" 0.000 6.224 eV
S49 A' 0.137 6.271 eV
S50 A' 0.087 6.290 eV
S51 A' 0.151 6.315 eV
S52 A' 0.000 6.358 eV
S53 A' 0.110 6.392 eV
S54 A" 0.002 6.417 eV
S55 A' 0.036 6.419 eV
S56 A' 0.007 6.438 eV
S57 A' 0.158 6.508 eV
S58 A' 0.077 6.532 eV
S59 A" 0.000 6.545 eV
S60 A' 0.208 6.559 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -217657.35

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 17:59:59

Added 2026-09-15 09:27:33

Legacy ID None

System


Full Name 5-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-7,11,18,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID141655051

Formula C34H13F3S4Se2

Mass 764.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2235 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM