5-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene (C34H13F3S4Se2) - excitons of #2241

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 1.952 3.862 eV
S2 A' 0.371 3.953 eV
S3 A' 0.037 3.962 eV
S4 A' 0.075 4.078 eV
S5 A' 2.494 4.098 eV
S6 A" 0.000 4.140 eV
S7 A' 0.012 4.516 eV
S8 A' 0.052 4.555 eV
S9 A' 0.038 4.626 eV
S10 A" 0.000 4.634 eV
S11 A' 0.368 4.672 eV
S12 A" 0.000 4.740 eV
S13 A' 0.026 4.828 eV
S14 A" 0.000 4.908 eV
S15 A' 0.060 4.911 eV
S16 A" 0.000 5.000 eV
S17 A' 0.099 5.113 eV
S18 A' 0.233 5.197 eV
S19 A' 0.056 5.237 eV
S20 A" 0.000 5.296 eV
S21 A' 0.001 5.297 eV
S22 A" 0.000 5.316 eV
S23 A' 0.206 5.337 eV
S24 A' 0.129 5.390 eV
S25 A" 0.000 5.391 eV
S26 A' 0.039 5.496 eV
S27 A' 0.185 5.546 eV
S28 A' 0.055 5.606 eV
S29 A' 0.023 5.647 eV
S30 A" 0.000 5.648 eV
S31 A" 0.000 5.687 eV
S32 A' 0.034 5.710 eV
S33 A' 0.022 5.764 eV
S34 A' 0.003 5.851 eV
S35 A" 0.000 5.882 eV
S36 A' 0.075 5.911 eV
S37 A' 0.012 5.984 eV
S38 A" 0.000 6.003 eV
S39 A' 0.035 6.006 eV
S40 A' 0.001 6.022 eV
S41 A" 0.000 6.053 eV
S42 A' 0.003 6.101 eV
S43 A' 0.023 6.144 eV
S44 A' 0.019 6.175 eV
S45 A" 0.000 6.182 eV
S46 A' 0.015 6.212 eV
S47 A' 0.011 6.237 eV
S48 A' 0.052 6.251 eV
S49 A' 0.140 6.290 eV
S50 A' 0.298 6.346 eV
S51 A' 0.008 6.386 eV
S52 A" 0.000 6.405 eV
S53 A' 0.013 6.408 eV
S54 A" 0.000 6.422 eV
S55 A' 0.124 6.429 eV
S56 A" 0.000 6.445 eV
S57 A' 0.001 6.482 eV
S58 A' 0.024 6.495 eV
S59 A" 0.002 6.564 eV
S60 A' 0.006 6.564 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -217657.36

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 18:21:17

Added 2026-09-15 09:32:25

Legacy ID None

System


Full Name 5-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2,4(8),5,9,13(21),14,16,19-nonaene

Short Name CID141655058

Formula C34H13F3S4Se2

Mass 764.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2241 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM