7-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C34H13F3S4Se2) - excitons of #2245

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.821 3.404 eV
S2 A' 0.720 3.853 eV
S3 A' 0.006 3.995 eV
S4 A' 0.007 4.165 eV
S5 A" 0.000 4.224 eV
S6 A' 0.083 4.338 eV
S7 A' 0.033 4.367 eV
S8 A' 0.013 4.542 eV
S9 A" 0.000 4.626 eV
S10 A' 0.462 4.644 eV
S11 A" 0.000 4.649 eV
S12 A' 0.003 4.723 eV
S13 A" 0.000 4.811 eV
S14 A' 0.108 4.908 eV
S15 A" 0.000 4.937 eV
S16 A' 0.421 5.025 eV
S17 A" 0.000 5.028 eV
S18 A' 0.029 5.079 eV
S19 A' 0.007 5.140 eV
S20 A' 0.057 5.203 eV
S21 A' 0.007 5.287 eV
S22 A" 0.000 5.332 eV
S23 A' 0.006 5.346 eV
S24 A' 0.123 5.411 eV
S25 A' 0.010 5.525 eV
S26 A" 0.000 5.540 eV
S27 A' 0.527 5.560 eV
S28 A" 0.000 5.614 eV
S29 A' 0.094 5.648 eV
S30 A' 0.168 5.652 eV
S31 A' 0.428 5.681 eV
S32 A' 0.232 5.727 eV
S33 A' 0.097 5.817 eV
S34 A' 0.165 5.856 eV
S35 A" 0.000 5.876 eV
S36 A' 0.034 5.903 eV
S37 A' 0.229 5.992 eV
S38 A" 0.000 5.996 eV
S39 A' 0.023 6.008 eV
S40 A' 0.124 6.024 eV
S41 A" 0.000 6.089 eV
S42 A' 0.261 6.097 eV
S43 A" 0.001 6.105 eV
S44 A" 0.000 6.125 eV
S45 A' 0.023 6.184 eV
S46 A' 0.001 6.210 eV
S47 A" 0.000 6.213 eV
S48 A' 0.047 6.238 eV
S49 A' 0.027 6.291 eV
S50 A' 0.058 6.346 eV
S51 A" 0.002 6.408 eV
S52 A' 0.192 6.413 eV
S53 A' 0.464 6.436 eV
S54 A' 0.008 6.473 eV
S55 A' 0.012 6.520 eV
S56 A" 0.000 6.532 eV
S57 A' 0.001 6.534 eV
S58 A' 0.056 6.577 eV
S59 A' 0.105 6.601 eV
S60 A' 0.194 6.615 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -217657.31

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 18:31:42

Added 2026-09-15 09:36:26

Legacy ID None

System


Full Name 7-Fluoro-6,17-bis(3-fluoro-1-benzoselenophen-2-yl)-5,11,16,22-tetrathiahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID141655062

Formula C34H13F3S4Se2

Mass 764.7 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2245 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM