4,5,6,7-Tetrafluoro-9-thiadecacyclo[25.6.2.02,10.03,8.011,32.014,31.017,30.018,23.024,29.028,33]pentatriaconta-1(33),2(10),3,5,7,11(32),12,14(31),15,17(30),18,20,22,24(29),25,27,34-heptadecaene (C34H12F4S) - excitons of #2252

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 0.012 3.482 eV
S2 A' 0.076 3.658 eV
S3 A' 0.571 4.259 eV
S4 A' 0.130 4.354 eV
S5 A' 1.156 4.509 eV
S6 A' 0.906 4.548 eV
S7 A' 0.068 4.722 eV
S8 A' 0.087 4.769 eV
S9 A' 0.263 4.836 eV
S10 A' 0.088 4.872 eV
S11 A' 0.068 5.073 eV
S12 A' 0.021 5.097 eV
S13 A' 0.024 5.159 eV
S14 A' 0.040 5.203 eV
S15 A' 0.090 5.246 eV
S16 A" 0.000 5.376 eV
S17 A' 0.552 5.376 eV
S18 A' 0.025 5.405 eV
S19 A' 0.013 5.505 eV
S20 A' 0.016 5.547 eV
S21 A' 0.029 5.664 eV
S22 A' 0.233 5.776 eV
S23 A' 0.043 5.791 eV
S24 A" 0.000 5.869 eV
S25 A' 0.053 5.891 eV
S26 A' 0.039 5.920 eV
S27 A' 0.013 5.937 eV
S28 A" 0.001 6.055 eV
S29 A' 0.573 6.060 eV
S30 A' 0.093 6.067 eV
S31 A' 0.013 6.091 eV
S32 A' 0.007 6.153 eV
S33 A' 0.076 6.221 eV
S34 A' 0.645 6.249 eV
S35 A' 0.231 6.313 eV
S36 A' 0.229 6.362 eV
S37 A' 0.015 6.396 eV
S38 A' 0.190 6.449 eV
S39 A" 0.000 6.476 eV
S40 A" 0.003 6.496 eV
S41 A' 0.168 6.522 eV
S42 A" 0.000 6.537 eV
S43 A' 0.013 6.539 eV
S44 A' 0.115 6.630 eV
S45 A' 0.056 6.653 eV
S46 A' 0.004 6.688 eV
S47 A" 0.000 6.688 eV
S48 A' 0.026 6.772 eV
S49 A' 0.032 6.802 eV
S50 A" 0.000 6.830 eV
S51 A' 0.032 6.845 eV
S52 A' 0.549 6.854 eV
S53 A' 0.012 6.879 eV
S54 A' 0.025 6.944 eV
S55 A' 0.133 6.979 eV
S56 A' 0.441 6.990 eV
S57 A" 0.000 7.006 eV
S58 A" 0.000 7.035 eV
S59 A' 0.127 7.055 eV
S60 A" 0.001 7.082 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -57146.14

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 19:33:01

Added 2026-09-15 09:43:05

Legacy ID None

System


Full Name 4,5,6,7-Tetrafluoro-9-thiadecacyclo[25.6.2.02,10.03,8.011,32.014,31.017,30.018,23.024,29.028,33]pentatriaconta-1(33),2(10),3,5,7,11(32),12,14(31),15,17(30),18,20,22,24(29),25,27,34-heptadecaene

Short Name CID148456540

Formula C34H12F4S

Mass 528.5 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2252 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM