7-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-5,11,22-trithia-16-selenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene (C34H13F3S5Se) - excitons of #2263

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A' 2.817 3.415 eV
S2 A' 0.727 3.839 eV
S3 A' 0.019 4.012 eV
S4 A' 0.004 4.157 eV
S5 A' 0.004 4.470 eV
S6 A' 0.112 4.500 eV
S7 A' 0.060 4.582 eV
S8 A' 0.353 4.658 eV
S9 A' 0.017 4.720 eV
S10 A" 0.000 4.728 eV
S11 A' 0.212 4.845 eV
S12 A" 0.000 4.900 eV
S13 A' 0.321 5.041 eV
S14 A' 0.043 5.082 eV
S15 A' 0.022 5.150 eV
S16 A" 0.000 5.216 eV
S17 A' 0.028 5.247 eV
S18 A' 0.022 5.282 eV
S19 A" 0.000 5.303 eV
S20 A" 0.000 5.311 eV
S21 A' 0.189 5.369 eV
S22 A" 0.000 5.394 eV
S23 A" 0.000 5.423 eV
S24 A' 0.161 5.449 eV
S25 A' 0.138 5.541 eV
S26 A' 0.057 5.601 eV
S27 A" 0.000 5.626 eV
S28 A' 0.354 5.660 eV
S29 A" 0.000 5.662 eV
S30 A' 0.319 5.675 eV
S31 A' 0.020 5.722 eV
S32 A' 0.075 5.783 eV
S33 A' 0.054 5.824 eV
S34 A" 0.000 5.829 eV
S35 A" 0.000 5.864 eV
S36 A' 0.360 5.865 eV
S37 A' 0.269 5.977 eV
S38 A' 0.051 6.013 eV
S39 A" 0.000 6.078 eV
S40 A' 0.179 6.079 eV
S41 A' 0.267 6.112 eV
S42 A' 0.000 6.168 eV
S43 A' 0.059 6.220 eV
S44 A' 0.005 6.251 eV
S45 A' 0.095 6.264 eV
S46 A' 0.153 6.312 eV
S47 A' 0.237 6.346 eV
S48 A" 0.000 6.414 eV
S49 A' 0.001 6.446 eV
S50 A' 0.109 6.459 eV
S51 A' 0.002 6.467 eV
S52 A" 0.001 6.470 eV
S53 A' 0.005 6.477 eV
S54 A" 0.000 6.533 eV
S55 A' 0.023 6.543 eV
S56 A' 0.003 6.586 eV
S57 A" 0.001 6.619 eV
S58 A" 0.002 6.640 eV
S59 A' 0.089 6.647 eV
S60 A" 0.001 6.669 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -163140.60

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 14:43:05

Added 2026-09-15 09:55:01

Legacy ID None

System


Full Name 7-Fluoro-6,17-bis(3-fluoro-1-benzothiophen-2-yl)-5,11,22-trithia-16-selenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,6,8,13(21),14,17,19-nonaene

Short Name CID162714704

Formula C34H13F3S5Se

Mass 717.7 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2263 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM