23-Fluoro-34,41-bis(3-fluorophenyl)hexadecacyclo[26.21.2.22,5.229,32.19,13.03,24.04,21.06,20.08,18.025,50.030,46.031,43.033,42.035,40.047,51.017,54]hexapentaconta-1(50),2,4,6(20),7,9,11,13(54),14,16,18,21,23,25,27,29(53),30(46),31(43),32(52),33,35,37,39,41,44,47(51),48,55-octacosaene (C68H31F3) - excitons of #2265

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 2.708 2.328 eV
S2 0.007 2.954 eV
S3 0.009 3.348 eV
S4 0.000 3.448 eV
S5 0.012 3.541 eV
S6 0.015 3.657 eV
S7 0.008 3.737 eV
S8 0.007 3.849 eV
S9 0.006 3.856 eV
S10 0.003 3.971 eV
S11 0.056 4.130 eV
S12 0.003 4.167 eV
S13 0.006 4.223 eV
S14 0.269 4.276 eV
S15 0.034 4.441 eV
S16 0.010 4.457 eV
S17 1.963 4.489 eV
S18 0.008 4.571 eV
S19 0.052 4.616 eV
S20 0.023 4.684 eV
S21 0.303 4.740 eV
S22 0.833 4.782 eV
S23 0.080 4.823 eV
S24 0.052 4.948 eV
S25 0.001 4.966 eV
S26 0.036 4.989 eV
S27 0.001 5.032 eV
S28 0.002 5.076 eV
S29 0.045 5.100 eV
S30 0.003 5.119 eV
S31 0.231 5.184 eV
S32 0.122 5.196 eV
S33 0.024 5.207 eV
S34 0.093 5.244 eV
S35 0.650 5.290 eV
S36 0.116 5.314 eV
S37 0.005 5.362 eV
S38 0.003 5.387 eV
S39 0.000 5.407 eV
S40 0.011 5.427 eV
S41 0.048 5.432 eV
S42 0.314 5.445 eV
S43 0.064 5.476 eV
S44 0.039 5.499 eV
S45 0.008 5.505 eV
S46 0.055 5.524 eV
S47 0.001 5.543 eV
S48 0.107 5.574 eV
S49 0.000 5.583 eV
S50 0.085 5.627 eV
S51 0.014 5.651 eV
S52 0.054 5.682 eV
S53 0.002 5.722 eV
S54 0.000 5.748 eV
S55 0.102 5.786 eV
S56 0.082 5.798 eV
S57 0.017 5.823 eV
S58 0.046 5.842 eV
S59 0.112 5.861 eV
S60 0.001 5.874 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -79154.09

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-12 04:47:19

Added 2026-09-15 09:57:04

Legacy ID None

System


Full Name 23-Fluoro-34,41-bis(3-fluorophenyl)hexadecacyclo[26.21.2.22,5.229,32.19,13.03,24.04,21.06,20.08,18.025,50.030,46.031,43.033,42.035,40.047,51.017,54]hexapentaconta-1(50),2,4,6(20),7,9,11,13(54),14,16,18,21,23,25,27,29(53),30(46),31(43),32(52),33,35,37,39,41,44,47(51),48,55-octacosaene

Short Name CID163542521

Formula C68H31F3

Mass 905.0 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2265 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM