6-(3,4-Difluorothiophen-2-yl)-17-(3-fluoro-4-methylthiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene (C27H11F3S4Se2) - excitons of #2267

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 0.210 3.302 eV
S2 0.399 3.758 eV
S3 0.268 3.793 eV
S4 0.255 3.905 eV
S5 0.453 4.073 eV
S6 1.638 4.171 eV
S7 0.010 4.484 eV
S8 0.438 4.506 eV
S9 0.479 4.542 eV
S10 0.037 4.625 eV
S11 0.113 4.787 eV
S12 0.016 4.928 eV
S13 0.010 4.939 eV
S14 0.002 5.034 eV
S15 0.008 5.048 eV
S16 0.057 5.106 eV
S17 0.011 5.139 eV
S18 0.019 5.166 eV
S19 0.021 5.247 eV
S20 0.025 5.272 eV
S21 0.032 5.332 eV
S22 0.093 5.434 eV
S23 0.016 5.514 eV
S24 0.007 5.568 eV
S25 0.007 5.584 eV
S26 0.004 5.602 eV
S27 0.002 5.653 eV
S28 0.004 5.657 eV
S29 0.039 5.667 eV
S30 0.037 5.686 eV
S31 0.003 5.742 eV
S32 0.014 5.788 eV
S33 0.021 5.823 eV
S34 0.043 5.848 eV
S35 0.038 5.865 eV
S36 0.061 5.891 eV
S37 0.007 5.993 eV
S38 0.051 6.011 eV
S39 0.009 6.045 eV
S40 0.040 6.072 eV
S41 0.087 6.142 eV
S42 0.023 6.169 eV
S43 0.021 6.202 eV
S44 0.027 6.227 eV
S45 0.003 6.266 eV
S46 0.083 6.300 eV
S47 0.003 6.325 eV
S48 0.041 6.337 eV
S49 0.017 6.382 eV
S50 0.004 6.402 eV
S51 0.018 6.425 eV
S52 0.003 6.454 eV
S53 0.072 6.469 eV
S54 0.007 6.520 eV
S55 0.036 6.538 eV
S56 0.004 6.557 eV
S57 0.003 6.588 eV
S58 0.016 6.602 eV
S59 0.018 6.639 eV
S60 0.013 6.661 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -210362.76

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-12 02:27:56

Added 2026-09-15 10:00:56

Legacy ID None

System


Full Name 6-(3,4-Difluorothiophen-2-yl)-17-(3-fluoro-4-methylthiophen-2-yl)-11,22-dithia-7,18-diselenahexacyclo[10.10.0.02,10.04,8.013,21.015,19]docosa-1(12),2(10),3,5,8,13(21),14,16,19-nonaene

Short Name CID164014379

Formula C27H11F3S4Se2

Mass 678.6 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2267 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM