3,4-Difluorotridecacyclo[34.6.6.02,7.08,41.09,14.015,40.016,21.022,39.023,28.029,38.030,35.037,42.043,48]octatetraconta-1,3,5,7,9,11,13,15(40),16,18,20,22(39),23,25,27,29(38),30,32,34,36,41,43,45,47-tetracosaene (C48H22F2) - excitons of #2275

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 0.001 3.251 eV
S2 0.040 3.386 eV
S3 0.010 3.650 eV
S4 0.028 3.754 eV
S5 0.003 3.933 eV
S6 0.141 4.028 eV
S7 1.726 4.078 eV
S8 1.626 4.088 eV
S9 0.051 4.346 eV
S10 0.001 4.504 eV
S11 0.009 4.560 eV
S12 0.022 4.598 eV
S13 0.065 4.650 eV
S14 0.009 4.791 eV
S15 0.026 4.855 eV
S16 0.016 4.976 eV
S17 0.112 4.993 eV
S18 0.025 5.015 eV
S19 0.052 5.042 eV
S20 0.156 5.078 eV
S21 0.002 5.125 eV
S22 0.014 5.247 eV
S23 0.186 5.263 eV
S24 0.168 5.269 eV
S25 0.084 5.297 eV
S26 0.188 5.305 eV
S27 0.469 5.321 eV
S28 0.469 5.334 eV
S29 0.124 5.347 eV
S30 0.037 5.371 eV
S31 0.044 5.397 eV
S32 0.011 5.423 eV
S33 0.136 5.447 eV
S34 0.074 5.456 eV
S35 0.048 5.487 eV
S36 0.027 5.492 eV
S37 0.018 5.522 eV
S38 0.229 5.584 eV
S39 0.115 5.586 eV
S40 0.328 5.618 eV
S41 0.040 5.702 eV
S42 0.038 5.723 eV
S43 0.004 5.757 eV
S44 0.018 5.774 eV
S45 0.001 5.799 eV
S46 0.008 5.884 eV
S47 0.002 5.928 eV
S48 0.003 6.037 eV
S49 0.009 6.066 eV
S50 0.010 6.116 eV
S51 0.000 6.132 eV
S52 0.045 6.155 eV
S53 0.075 6.168 eV
S54 0.005 6.189 eV
S55 0.026 6.237 eV
S56 0.011 6.244 eV
S57 0.125 6.259 eV
S58 0.370 6.291 eV
S59 0.335 6.339 eV
S60 0.002 6.358 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -55553.16

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 11:19:14

Added 2026-09-15 10:08:49

Legacy ID None

System


Full Name 3,4-Difluorotridecacyclo[34.6.6.02,7.08,41.09,14.015,40.016,21.022,39.023,28.029,38.030,35.037,42.043,48]octatetraconta-1,3,5,7,9,11,13,15(40),16,18,20,22(39),23,25,27,29(38),30,32,34,36,41,43,45,47-tetracosaene

Short Name CID175868777

Formula C48H22F2

Mass 636.7 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2275 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM