29,33-Dinitrononacyclo[18.10.2.22,5.03,16.04,13.06,11.017,31.022,27.028,32]tetratriaconta-1(30),2(34),3(16),4(13),5(33),6,8,10,14,17(31),18,20(32),22,24,26,28-hexadecaene-12,21-dione (C34H14N2O6) - excitons of #2286

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A" 1.311 2.725 eV
S2 A" 0.000 3.392 eV
S3 A' 0.000 3.395 eV
S4 A" 0.020 3.615 eV
S5 A' 0.013 3.673 eV
S6 A" 0.000 3.726 eV
S7 A' 0.022 3.906 eV
S8 A" 0.005 3.920 eV
S9 A' 0.037 4.006 eV
S10 A' 0.003 4.118 eV
S11 A" 0.031 4.150 eV
S12 A" 0.006 4.259 eV
S13 A' 0.078 4.327 eV
S14 A" 0.033 4.456 eV
S15 A' 0.012 4.478 eV
S16 A" 0.000 4.581 eV
S17 A' 0.000 4.589 eV
S18 A" 0.004 4.621 eV
S19 A' 0.000 4.702 eV
S20 A" 0.042 5.013 eV
S21 A' 0.082 5.175 eV
S22 A" 0.010 5.179 eV
S23 A' 0.002 5.246 eV
S24 A" 0.319 5.270 eV
S25 A" 0.001 5.290 eV
S26 A' 0.026 5.321 eV
S27 A' 0.012 5.362 eV
S28 A" 0.185 5.466 eV
S29 A' 0.167 5.472 eV
S30 A' 0.082 5.544 eV
S31 A" 0.575 5.564 eV
S32 A" 0.194 5.584 eV
S33 A' 0.077 5.639 eV
S34 A" 0.000 5.704 eV
S35 A" 0.006 5.720 eV
S36 A' 0.019 5.730 eV
S37 A" 0.290 5.786 eV
S38 A' 0.019 5.798 eV
S39 A" 0.592 5.813 eV
S40 A' 0.176 5.842 eV
S41 A' 0.009 5.859 eV
S42 A" 0.043 5.898 eV
S43 A' 0.004 5.903 eV
S44 A" 0.103 5.903 eV
S45 A' 0.030 5.932 eV
S46 A" 0.057 5.953 eV
S47 A' 0.057 6.038 eV
S48 A" 0.317 6.048 eV
S49 A' 0.075 6.066 eV
S50 A' 0.010 6.096 eV
S51 A' 0.024 6.119 eV
S52 A" 0.013 6.123 eV
S53 A" 0.225 6.138 eV
S54 A' 0.096 6.148 eV
S55 A' 0.025 6.208 eV
S56 A" 0.016 6.211 eV
S57 A" 0.000 6.250 eV
S58 A" 0.007 6.297 eV
S59 A' 0.150 6.317 eV
S60 A" 0.013 6.318 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -50730.76

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 22:36:28

Added 2026-09-15 10:18:34

Legacy ID None

System


Full Name 29,33-Dinitrononacyclo[18.10.2.22,5.03,16.04,13.06,11.017,31.022,27.028,32]tetratriaconta-1(30),2(34),3(16),4(13),5(33),6,8,10,14,17(31),18,20(32),22,24,26,28-hexadecaene-12,21-dione

Short Name CID49852

Formula C34H14N2O6

Mass 546.5 u

Point Group Cs

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2286 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM