8,21-Diphenyl-5,13,18,26-tetrathiaheptacyclo[14.10.0.03,14.04,12.06,11.017,25.019,24]hexacosa-1(16),2,4(12),6(11),7,9,14,17(25),19(24),20,22-undecaene (C34H18S4) - excitons of #2295

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 B 1.691 3.725 eV
S2 B 0.765 4.078 eV
S3 A 0.000 4.358 eV
S4 B 0.108 4.567 eV
S5 A 0.000 4.676 eV
S6 B 0.198 4.828 eV
S7 B 0.589 4.834 eV
S8 A 0.000 4.982 eV
S9 A 0.000 4.993 eV
S10 A 0.000 5.144 eV
S11 B 0.447 5.197 eV
S12 A 0.000 5.262 eV
S13 B 0.060 5.267 eV
S14 B 0.009 5.442 eV
S15 A 0.000 5.495 eV
S16 A 0.000 5.507 eV
S17 B 0.372 5.508 eV
S18 B 0.001 5.554 eV
S19 A 0.000 5.601 eV
S20 B 0.030 5.632 eV
S21 B 0.255 5.705 eV
S22 A 0.000 5.732 eV
S23 B 0.472 5.747 eV
S24 A 0.000 5.751 eV
S25 A 0.000 5.841 eV
S26 B 0.144 6.040 eV
S27 A 0.004 6.044 eV
S28 B 0.013 6.086 eV
S29 B 0.224 6.135 eV
S30 A 0.020 6.144 eV
S31 B 0.111 6.167 eV
S32 A 0.003 6.171 eV
S33 A 0.007 6.187 eV
S34 B 0.462 6.270 eV
S35 A 0.000 6.379 eV
S36 A 0.000 6.460 eV
S37 B 0.334 6.477 eV
S38 B 0.535 6.498 eV
S39 B 0.023 6.519 eV
S40 A 0.018 6.523 eV
S41 B 0.118 6.569 eV
S42 A 0.000 6.588 eV
S43 B 0.015 6.600 eV
S44 A 0.000 6.612 eV
S45 B 0.157 6.667 eV
S46 A 0.000 6.673 eV
S47 B 0.066 6.685 eV
S48 A 0.000 6.718 eV
S49 A 0.001 6.737 eV
S50 B 0.023 6.740 eV
S51 A 0.000 6.758 eV
S52 B 0.413 6.766 eV
S53 A 0.000 6.771 eV
S54 B 0.036 6.805 eV
S55 A 0.000 6.809 eV
S56 B 0.007 6.838 eV
S57 A 0.000 6.884 eV
S58 A 0.002 6.911 eV
S59 B 0.143 6.991 eV
S60 B 0.058 7.002 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -78881.39

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 23:00:28

Added 2026-09-15 10:25:14

Legacy ID None

System


Full Name 8,21-Diphenyl-5,13,18,26-tetrathiaheptacyclo[14.10.0.03,14.04,12.06,11.017,25.019,24]hexacosa-1(16),2,4(12),6(11),7,9,14,17(25),19(24),20,22-undecaene

Short Name CID57913333

Formula C34H18S4

Mass 554.8 u

Point Group C2

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2295 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM