7,18-Bis(2,4-difluorophenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C36H14F4N2O4) - excitons of #2304

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A" 1.228 2.961 eV
S2 A" 0.000 3.891 eV
S3 A" 0.000 4.104 eV
S4 A' 0.017 4.125 eV
S5 A" 0.000 4.155 eV
S6 A' 0.052 4.156 eV
S7 A" 0.000 4.371 eV
S8 A' 0.006 4.454 eV
S9 A' 0.000 4.471 eV
S10 A" 0.000 4.484 eV
S11 A' 0.000 4.596 eV
S12 A' 0.000 4.611 eV
S13 A" 0.000 4.617 eV
S14 A" 0.000 4.795 eV
S15 A' 0.003 4.919 eV
S16 A" 0.000 4.949 eV
S17 A' 0.001 5.153 eV
S18 A" 0.000 5.355 eV
S19 A" 0.072 5.542 eV
S20 A' 0.003 5.543 eV
S21 A" 0.000 5.625 eV
S22 A' 0.435 5.638 eV
S23 A' 0.023 5.770 eV
S24 A" 0.000 5.804 eV
S25 A' 0.000 5.855 eV
S26 A' 0.000 5.894 eV
S27 A' 0.011 5.981 eV
S28 A" 0.311 6.007 eV
S29 A" 0.281 6.048 eV
S30 A" 0.019 6.069 eV
S31 A' 0.009 6.085 eV
S32 A" 0.258 6.123 eV
S33 A' 0.001 6.143 eV
S34 A" 0.001 6.156 eV
S35 A' 0.263 6.224 eV
S36 A" 0.066 6.225 eV
S37 A' 0.003 6.298 eV
S38 A" 0.007 6.305 eV
S39 A' 0.018 6.312 eV
S40 A" 0.585 6.384 eV
S41 A" 0.692 6.471 eV
S42 A' 0.001 6.482 eV
S43 A' 0.000 6.504 eV
S44 A" 1.219 6.511 eV
S45 A' 0.000 6.535 eV
S46 A" 0.081 6.543 eV
S47 A' 0.001 6.546 eV
S48 A' 0.000 6.604 eV
S49 A" 0.184 6.639 eV
S50 A' 0.000 6.650 eV
S51 A' 0.025 6.689 eV
S52 A" 0.084 6.693 eV
S53 A' 0.107 6.701 eV
S54 A" 0.194 6.707 eV
S55 A' 0.002 6.747 eV
S56 A" 0.135 6.753 eV
S57 A' 0.421 6.757 eV
S58 A" 0.233 6.794 eV
S59 A' 0.001 6.827 eV
S60 A' 0.004 6.844 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -59586.11

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 06:39:18

Added 2026-09-15 10:32:08

Legacy ID None

System


Full Name 7,18-Bis(2,4-difluorophenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID58660864

Formula C36H14F4N2O4

Mass 614.5 u

Point Group Cs

Orientation zy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2304 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM