7-(2-Methylphenyl)-18-[2-(trifluoromethyl)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C38H19F3N2O4) - excitons of #2306

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 1.236 2.959 eV
S2 0.000 3.892 eV
S3 0.000 4.049 eV
S4 0.000 4.130 eV
S5 0.066 4.150 eV
S6 0.000 4.180 eV
S7 0.000 4.263 eV
S8 0.000 4.397 eV
S9 0.000 4.470 eV
S10 0.000 4.496 eV
S11 0.000 4.541 eV
S12 0.000 4.615 eV
S13 0.000 4.624 eV
S14 0.001 4.755 eV
S15 0.000 4.975 eV
S16 0.009 5.010 eV
S17 0.000 5.177 eV
S18 0.000 5.287 eV
S19 0.008 5.528 eV
S20 0.019 5.547 eV
S21 0.010 5.632 eV
S22 0.437 5.632 eV
S23 0.013 5.786 eV
S24 0.000 5.809 eV
S25 0.001 5.842 eV
S26 0.001 5.906 eV
S27 0.001 5.959 eV
S28 0.004 5.992 eV
S29 0.019 6.001 eV
S30 0.295 6.041 eV
S31 0.009 6.076 eV
S32 0.073 6.108 eV
S33 0.009 6.118 eV
S34 0.239 6.123 eV
S35 0.094 6.137 eV
S36 0.000 6.161 eV
S37 0.251 6.229 eV
S38 0.007 6.274 eV
S39 0.024 6.312 eV
S40 0.017 6.317 eV
S41 0.637 6.357 eV
S42 0.177 6.384 eV
S43 0.105 6.404 eV
S44 0.204 6.432 eV
S45 0.000 6.485 eV
S46 1.706 6.499 eV
S47 0.084 6.507 eV
S48 0.000 6.538 eV
S49 0.001 6.602 eV
S50 0.000 6.610 eV
S51 0.044 6.645 eV
S52 0.056 6.685 eV
S53 0.027 6.694 eV
S54 0.547 6.719 eV
S55 0.008 6.737 eV
S56 0.007 6.756 eV
S57 0.312 6.760 eV
S58 0.089 6.790 eV
S59 0.015 6.801 eV
S60 0.191 6.814 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -59024.76

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 08:46:07

Added 2026-09-15 10:34:08

Legacy ID None

System


Full Name 7-(2-Methylphenyl)-18-[2-(trifluoromethyl)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID58660868

Formula C38H19F3N2O4

Mass 624.6 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2306 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM