7,18-Bis(3,5-dimethylphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C40H26N2O4) - excitons of #2314

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 1.251 2.960 eV
S2 0.000 3.895 eV
S3 0.000 4.057 eV
S4 0.000 4.061 eV
S5 0.000 4.134 eV
S6 0.052 4.153 eV
S7 0.009 4.154 eV
S8 0.000 4.162 eV
S9 0.000 4.394 eV
S10 0.000 4.408 eV
S11 0.000 4.414 eV
S12 0.000 4.473 eV
S13 0.000 4.530 eV
S14 0.000 4.549 eV
S15 0.000 4.622 eV
S16 0.000 4.734 eV
S17 0.017 4.947 eV
S18 0.000 5.228 eV
S19 0.004 5.414 eV
S20 0.004 5.415 eV
S21 0.462 5.629 eV
S22 0.000 5.642 eV
S23 0.008 5.804 eV
S24 0.000 5.811 eV
S25 0.000 5.832 eV
S26 0.000 5.924 eV
S27 0.019 5.964 eV
S28 0.000 5.978 eV
S29 0.002 5.982 eV
S30 0.003 5.988 eV
S31 0.010 5.990 eV
S32 0.000 5.994 eV
S33 0.000 5.995 eV
S34 0.013 6.007 eV
S35 0.282 6.058 eV
S36 0.428 6.128 eV
S37 0.048 6.142 eV
S38 0.000 6.167 eV
S39 0.000 6.206 eV
S40 0.001 6.222 eV
S41 0.003 6.225 eV
S42 0.005 6.230 eV
S43 0.001 6.232 eV
S44 0.229 6.234 eV
S45 0.000 6.324 eV
S46 1.323 6.388 eV
S47 0.022 6.445 eV
S48 0.000 6.454 eV
S49 1.967 6.474 eV
S50 0.020 6.483 eV
S51 0.000 6.534 eV
S52 0.003 6.536 eV
S53 0.001 6.543 eV
S54 0.000 6.600 eV
S55 0.107 6.682 eV
S56 0.631 6.715 eV
S57 0.004 6.745 eV
S58 0.000 6.760 eV
S59 0.002 6.770 eV
S60 0.244 6.772 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -53060.12

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 07:21:20

Added 2026-09-15 10:44:09

Legacy ID None

System


Full Name 7,18-Bis(3,5-dimethylphenyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID62555

Formula C40H26N2O4

Mass 598.7 u

Point Group C1

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2314 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM