6,42,48-Triazatridecacyclo[25.18.2.139,42.02,22.05,21.07,20.08,17.010,15.024,46.028,41.031,40.033,38.043,47]octatetraconta-1(45),2(22),3,5(21),7(20),8(17),10,12,14,18,24(46),25,27(47),28(41),29,31(40),33,35,37,39(48),43-henicosaene-9,16,23,32-tetrone (C45H19N3O4) - excitons of #2320

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 1.234 2.575 eV
S2 0.154 3.214 eV
S3 0.000 3.385 eV
S4 0.098 3.459 eV
S5 0.000 3.487 eV
S6 0.000 3.496 eV
S7 0.424 3.609 eV
S8 0.000 3.771 eV
S9 0.018 3.826 eV
S10 0.051 3.860 eV
S11 0.016 3.952 eV
S12 0.004 4.005 eV
S13 0.063 4.175 eV
S14 0.317 4.276 eV
S15 0.227 4.317 eV
S16 0.341 4.358 eV
S17 0.035 4.528 eV
S18 0.045 4.580 eV
S19 0.126 4.654 eV
S20 0.083 4.740 eV
S21 0.016 4.806 eV
S22 0.040 4.913 eV
S23 0.135 5.002 eV
S24 0.534 5.017 eV
S25 0.070 5.089 eV
S26 0.124 5.164 eV
S27 0.001 5.195 eV
S28 0.153 5.220 eV
S29 0.261 5.290 eV
S30 0.002 5.332 eV
S31 0.028 5.388 eV
S32 0.390 5.425 eV
S33 0.026 5.455 eV
S34 0.056 5.515 eV
S35 0.000 5.522 eV
S36 0.095 5.536 eV
S37 0.080 5.617 eV
S38 0.000 5.628 eV
S39 0.035 5.648 eV
S40 0.167 5.660 eV
S41 0.003 5.665 eV
S42 0.103 5.724 eV
S43 0.005 5.728 eV
S44 0.073 5.757 eV
S45 0.403 5.779 eV
S46 0.015 5.792 eV
S47 0.276 5.822 eV
S48 0.000 5.859 eV
S49 0.054 5.870 eV
S50 0.077 5.888 eV
S51 0.043 5.927 eV
S52 0.017 5.940 eV
S53 0.011 5.998 eV
S54 0.001 6.034 eV
S55 0.022 6.044 eV
S56 0.128 6.065 eV
S57 0.084 6.095 eV
S58 0.118 6.125 eV
S59 0.000 6.138 eV
S60 0.000 6.168 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -59618.38

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 14:10:04

Added 2026-09-15 10:49:43

Legacy ID None

System


Full Name 6,42,48-Triazatridecacyclo[25.18.2.139,42.02,22.05,21.07,20.08,17.010,15.024,46.028,41.031,40.033,38.043,47]octatetraconta-1(45),2(22),3,5(21),7(20),8(17),10,12,14,18,24(46),25,27(47),28(41),29,31(40),33,35,37,39(48),43-henicosaene-9,16,23,32-tetrone

Short Name CID75287

Formula C45H19N3O4

Mass 665.7 u

Point Group C1

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2320 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM