7-(2,2-Difluoro-1,3-benzodioxol-5-yl)-18-(2-fluoro-2-methyl-1,3-benzodioxol-5-yl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone (C39H17F3N2O8) - excitons of #2325

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 1.266 2.958 eV
S2 0.000 3.810 eV
S3 0.000 3.891 eV
S4 0.000 4.083 eV
S5 0.001 4.132 eV
S6 0.058 4.149 eV
S7 0.008 4.153 eV
S8 0.000 4.304 eV
S9 0.000 4.400 eV
S10 0.000 4.469 eV
S11 0.000 4.546 eV
S12 0.000 4.590 eV
S13 0.000 4.604 eV
S14 0.000 4.658 eV
S15 0.000 4.762 eV
S16 0.000 4.922 eV
S17 0.009 5.026 eV
S18 0.000 5.290 eV
S19 0.088 5.323 eV
S20 0.064 5.391 eV
S21 0.099 5.616 eV
S22 0.000 5.626 eV
S23 0.014 5.634 eV
S24 0.348 5.641 eV
S25 0.009 5.790 eV
S26 0.000 5.802 eV
S27 0.000 5.857 eV
S28 0.000 5.908 eV
S29 0.012 5.976 eV
S30 0.003 5.980 eV
S31 0.022 6.003 eV
S32 0.363 6.042 eV
S33 0.001 6.075 eV
S34 0.414 6.111 eV
S35 0.004 6.142 eV
S36 0.020 6.145 eV
S37 0.014 6.152 eV
S38 0.001 6.161 eV
S39 0.006 6.185 eV
S40 0.252 6.229 eV
S41 0.097 6.252 eV
S42 0.003 6.312 eV
S43 0.708 6.383 eV
S44 0.013 6.433 eV
S45 0.007 6.440 eV
S46 1.475 6.489 eV
S47 0.495 6.492 eV
S48 0.214 6.502 eV
S49 0.045 6.509 eV
S50 0.002 6.528 eV
S51 0.003 6.602 eV
S52 0.019 6.667 eV
S53 0.075 6.685 eV
S54 0.119 6.701 eV
S55 0.332 6.702 eV
S56 0.246 6.744 eV
S57 0.132 6.758 eV
S58 0.004 6.765 eV
S59 0.162 6.771 eV
S60 0.016 6.799 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -68217.71

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 16:17:57

Added 2026-09-15 10:54:20

Legacy ID None

System


Full Name 7-(2,2-Difluoro-1,3-benzodioxol-5-yl)-18-(2-fluoro-2-methyl-1,3-benzodioxol-5-yl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone

Short Name CID89252641

Formula C39H17F3N2O8

Mass 698.6 u

Point Group C1

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2325 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM