11,26-Difluoro-7,18-diphenyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2(26),3,5(25),9,11,13,15,20(24),21-decaene-6,8,17,19-tetrone (C36H16F2N2O4) - excitons of #2327

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A 1.275 3.048 eV
S2 B 0.003 3.956 eV
S3 B 0.045 4.054 eV
S4 B 0.000 4.089 eV
S5 B 0.019 4.115 eV
S6 B 0.009 4.124 eV
S7 A 0.003 4.394 eV
S8 B 0.000 4.460 eV
S9 A 0.001 4.543 eV
S10 B 0.000 4.572 eV
S11 A 0.000 4.590 eV
S12 B 0.000 4.600 eV
S13 A 0.000 4.630 eV
S14 A 0.001 4.664 eV
S15 A 0.001 4.773 eV
S16 B 0.001 4.885 eV
S17 B 0.011 5.011 eV
S18 B 0.007 5.324 eV
S19 A 0.077 5.571 eV
S20 B 0.420 5.580 eV
S21 B 0.001 5.608 eV
S22 B 0.001 5.611 eV
S23 A 0.015 5.699 eV
S24 B 0.017 5.772 eV
S25 A 0.000 5.883 eV
S26 B 0.075 5.934 eV
S27 B 0.004 5.956 eV
S28 B 0.037 5.967 eV
S29 B 0.014 6.001 eV
S30 A 0.010 6.070 eV
S31 A 0.509 6.129 eV
S32 B 0.184 6.176 eV
S33 A 0.001 6.221 eV
S34 B 0.001 6.228 eV
S35 A 0.004 6.229 eV
S36 B 0.001 6.254 eV
S37 A 0.007 6.295 eV
S38 A 0.078 6.300 eV
S39 B 0.037 6.345 eV
S40 B 0.000 6.360 eV
S41 A 0.501 6.373 eV
S42 B 0.044 6.420 eV
S43 A 0.185 6.458 eV
S44 A 0.185 6.465 eV
S45 B 0.001 6.466 eV
S46 A 0.200 6.494 eV
S47 A 0.234 6.541 eV
S48 A 1.042 6.556 eV
S49 A 0.796 6.603 eV
S50 A 0.000 6.682 eV
S51 B 0.009 6.729 eV
S52 A 0.455 6.737 eV
S53 B 0.210 6.747 eV
S54 A 0.181 6.752 eV
S55 B 0.029 6.754 eV
S56 B 0.004 6.792 eV
S57 A 0.207 6.806 eV
S58 B 0.002 6.815 eV
S59 A 0.008 6.839 eV
S60 A 0.065 6.848 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -54183.69

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 03:43:00

Added 2026-09-15 10:56:30

Legacy ID None

System


Full Name 11,26-Difluoro-7,18-diphenyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2(26),3,5(25),9,11,13,15,20(24),21-decaene-6,8,17,19-tetrone

Short Name CID89326722

Formula C36H16F2N2O4

Mass 578.5 u

Point Group C2

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2327 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM