Mg-tetraphenylporphyrin (C44H28MgN4) - excitons of #2340

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 0.001 2.384 eV
S2 0.001 2.385 eV
S3 2.465 3.927 eV
S4 2.452 3.929 eV
S5 0.000 4.252 eV
S6 0.000 4.318 eV
S7 0.366 4.375 eV
S8 0.367 4.377 eV
S9 0.000 4.607 eV
S10 0.000 4.756 eV
S11 0.000 4.794 eV
S12 0.004 4.887 eV
S13 0.005 4.890 eV
S14 0.034 4.918 eV
S15 0.053 4.931 eV
S16 0.001 4.941 eV
S17 0.013 4.972 eV
S18 0.005 4.977 eV
S19 0.383 5.022 eV
S20 0.354 5.028 eV
S21 0.000 5.058 eV
S22 0.000 5.059 eV
S23 0.000 5.136 eV
S24 0.014 5.153 eV
S25 0.030 5.171 eV
S26 0.020 5.176 eV
S27 0.006 5.196 eV
S28 0.005 5.222 eV
S29 0.002 5.226 eV
S30 0.001 5.237 eV
S31 0.014 5.261 eV
S32 0.041 5.278 eV
S33 0.040 5.285 eV
S34 0.100 5.289 eV
S35 0.007 5.320 eV
S36 0.025 5.326 eV
S37 0.001 5.356 eV
S38 0.016 5.390 eV
S39 0.062 5.413 eV
S40 0.030 5.421 eV
S41 0.102 5.431 eV
S42 0.011 5.437 eV
S43 0.000 5.451 eV
S44 0.000 5.468 eV
S45 0.046 5.490 eV
S46 0.000 5.505 eV
S47 0.001 5.506 eV
S48 0.000 5.554 eV
S49 0.000 5.562 eV
S50 0.000 5.620 eV
S51 0.000 5.631 eV
S52 0.001 5.636 eV
S53 0.000 5.654 eV
S54 0.002 5.698 eV
S55 0.004 5.713 eV
S56 0.000 5.738 eV
S57 0.007 5.744 eV
S58 0.005 5.749 eV
S59 0.000 5.843 eV
S60 0.000 5.892 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -57475.25

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-11 15:06:47

Added 2026-09-15 11:10:33

Legacy ID None

System


Full Name Mg-tetraphenylporphyrin

Short Name MgTPP

Formula C44H28MgN4

Mass 637.0 u

Point Group D4

Orientation yx

Further Reading

Further Reading Mg-tetraphenylporphyrin

  1. Charge-promoted self-metalation of porphyrins on an oxide surface

    L. Egger, M. Hollerer, C. Kern, H. Herrmann, P. Hurdax, A. Haags, X. Yang, A. Gottwald, M. Richter, S. Soubatch, F. S. Tautz, G. Koller, P. Puschnig, M. G. Ramsey, and M. Sterrer

    Angew. Chem. Int. Ed. 60, 5078 (2021)

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
47 B3LYP 6-31G* NWChem 0.0 0.0 43
194 6-31G* NWChem -1.0 0.5 194
391 6-31G* NWChem 0.0 0.0 397
797 cc-pVTZ NWChem 0.0 0.0
928 cc-pVTZ Orca 0.0 0.0
2340 CAM-B3LYP def2-TZVP Orca 0.0 0.0
129 HSE06 6-31G* NWChem 0.0 0.0 127
198 6-31G* NWChem -2.0 0.0 198
88 PBE 6-31G* NWChem 0.0 0.0 85

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM