Tridecacyclo[18.18.2.02,35.03,8.04,40.05,18.06,15.07,12.09,34.023,39.025,38.028,37.031,36]tetraconta-1(38),2(35),3(8),4,6(15),7(12),9(34),10,13,16,18,20(40),21,23(39),24,26,28(37),29,31(36),32-icosaene (C40H16) - excitons of #2370

CAM-B3LYP def2-TZVP 60 roots q = 0

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES Orbitals Excitons

S1 A1 0.000 3.060 eV
S2 B2 0.362 3.159 eV
S3 B2 0.006 3.924 eV
S4 A1 0.129 4.043 eV
S5 B2 0.042 4.054 eV
S6 A1 0.805 4.105 eV
S7 A1 0.081 4.266 eV
S8 B2 1.745 4.289 eV
S9 A1 0.033 4.400 eV
S10 B2 0.077 4.421 eV
S11 A1 0.009 4.463 eV
S12 B2 0.090 4.527 eV
S13 A1 0.014 4.753 eV
S14 B2 0.052 4.819 eV
S15 A1 0.003 4.923 eV
S16 B2 0.024 4.973 eV
S17 B2 0.063 5.117 eV
S18 A1 0.006 5.143 eV
S19 B2 0.062 5.195 eV
S20 A1 0.030 5.205 eV
S21 A1 0.095 5.317 eV
S22 B2 0.035 5.368 eV
S23 B2 0.001 5.430 eV
S24 A1 0.072 5.477 eV
S25 B2 0.033 5.522 eV
S26 B2 0.205 5.568 eV
S27 A1 0.007 5.570 eV
S28 B2 0.017 5.660 eV
S29 A1 0.015 5.686 eV
S30 B2 0.016 5.774 eV
S31 A1 0.039 5.794 eV
S32 A1 0.006 5.831 eV
S33 B2 0.000 5.885 eV
S34 B2 0.014 5.911 eV
S35 B2 0.042 5.966 eV
S36 B2 0.043 6.022 eV
S37 A1 0.143 6.083 eV
S38 A1 0.038 6.115 eV
S39 B2 0.019 6.172 eV
S40 A1 0.307 6.214 eV
S41 B1 0.000 6.238 eV
S42 A1 0.046 6.298 eV
S43 A1 0.072 6.313 eV
S44 A2 0.000 6.348 eV
S45 A1 0.008 6.374 eV
S46 B2 2.094 6.405 eV
S47 B2 0.004 6.420 eV
S48 A1 0.222 6.487 eV
S49 B2 2.319 6.502 eV
S50 A1 0.306 6.541 eV
S51 B2 0.009 6.570 eV
S52 B1 0.000 6.572 eV
S53 A1 0.104 6.608 eV
S54 B2 0.004 6.618 eV
S55 A2 0.000 6.663 eV
S56 A1 0.202 6.691 eV
S57 B2 0.034 6.723 eV
S58 B1 0.001 6.730 eV
S59 A1 0.671 6.770 eV
S60 B1 0.000 6.773 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -41729.22

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2026-09-10 17:01:43

Added 2026-09-15 11:37:54

Legacy ID None

System


Full Name Tridecacyclo[18.18.2.02,35.03,8.04,40.05,18.06,15.07,12.09,34.023,39.025,38.028,37.031,36]tetraconta-1(38),2(35),3(8),4,6(15),7(12),9(34),10,13,16,18,20(40),21,23(39),24,26,28(37),29,31(36),32-icosaene

Short Name phenanthro[3,4,5,6-efghi]ovalene

Formula C40H16

Mass 496.6 u

Point Group C2v

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
2370 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM